Iarc no component of this product present at levels greater than or equal to 0. Preparation, properties, and safe handling of commercial. Chemical labels are available in paper to help you balance your costquality label needs. Occupational polyneuropathy has resulted from hexane exposures as low as 500 ppm, but the minimum levels of n hexane that are neurotoxic in humans havent been established. Although chemists will still need to handle tbuli and its brethren with care, deep eutectic solvents can help them to guide tbulis cannonball reactivity with more arrowlike precision. Sigmaaldrich 9386 page 3 of 7 methods and materials for containment and cleaning up contain spillage, and then collect with noncombustible absorbent material, e. Extreme high moderate low section 1 chemical product and company identification. Quenching of pyrophoric materials university of california. Safety data sheet according to 29cfr19101200 and ghs rev.
Nearly continuous exposure of animals at 250 ppm has caused. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Quenching of tbutyllithium tbuli remaining in bottle or left after reactions quenching of pyrophoric liquids, such as secbuli, nbuli, grignard reagents, remaining in bottle or left after reactions quenching of pyrophoric solids, such as finely divided metals magnesium, zirconium, nonmetals white phosphorus. Hexanes typically contain a high proportion of nhexane.
Hazard statements h225 highly flammable liquid and vapour. Material safety data sheet hexane 7 section 16 other information msds creation date. Hexanes, acs safety data sheet according to federal register vol. Reproductive effects experiments have shown reproductive toxicity effects on laboratory animals. The starting material is fairly soluble in the solvent, but not at all in hexane, which is how the nbuli usually comes, i was wondering if this could be an issue. Butyllithium 15% solution in nhexane for synthesis find msds or sds, a coa, data sheets and more information. Relevant identified uses of the substance or mixture and uses advised against use of the substancemixture. The major use n hexane is to extract vegetable oils from crops due to its narrow distillation range and selective power. The term may refer to any of the five structural isomers with that formula, or to a mixture of them. In iupac nomenclature, however, hexane is the unbranched isomer nhexane. Hexane 25 gkg rat 3000 mgkg rabbit 48000 ppm rat 4 h. Numerous examples of the use of n buli are to be found in org.
Chemical intermediate for research and industrial use only 1. Hexane is expected to rapidly volatilize leaving a deposit of n butyllithium behind. Also, it is broadly employed as a strong base in the synthesis of organic compounds as in the pharmaceutical industry. Hexane material safety data sheet cas no 110543 sdsmsds. That was katrina kramer, speaking with eva hevia from the university of strathclyde about tertbutyl lithium or tbuli. It is widely used as a polymerization initiator in the production of elastomers such as polybutadiene or styrenebutadienestyrene sbs. Flammable limits in air not applicable for formulation. Solubility nbutyllithium is miscible in all proportions with aliphatic, aromatic, and ethereal solvents. Our msds database is an easy to use, do it yourself tool, and best of all. Heating may cause a fire in contact with water releases flammable gases which may ignite spontaneously may cause fire or explosion. Your new online msds binder is a place for you to store the material safety data sheets you need to. The term hexanes cas 110543 refers to a hydrocarbon distillation fraction that contains a mixture of linear and branched hexane isomers. Lithium hydroxide, the oxidationhydrolysis product, is considered moderately toxic. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database.
Identification of the substancemixture and of the companyundertaking 1. Designed to stick to oily, greasy or irregular surfaces. Product and company identification product name n butyllithium, 2. The interdependent properties, such as pyrophoricity, solubility, stability, and aggregation, are tabulated and discussed. Hexane n hexane 20 72 as published by safe work australia. Hexane not listed as a carcinogen by acgih, iarc, ntp, or ca prop 65.
Nearly continuous exposure of animals at 250 ppm has caused neurotoxic effects. Shop online for a wide selection of nbutyllithium, 2. Butyllithium 15% solution in n hexane for synthesis find msds or sds, a coa, data sheets and more information. Common names for these solvents are commercial hexane, mixed hexanes, petroleum ether, and petroleum naphtha. Twa the timeweighted average airborne concentration over an eighthour working day, for a fiveday working week over an entire working life. To use this application, you will need the latest version of adobe reader. Hexane is expected to rapidly volatilize leaving a deposit of nbutyllithium behind.
Check availability and compare product details hexane chromasolv, for hplc. Sensitivity to static discharge yes sensitivity to static impact not applicable. The starting material is fairly soluble in the solvent, but not at all in hexane, which is how the n buli usually comes, i was wondering if this could be an issue. Click to download the latest version of adobe reader.
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